Showing posts with label alchemy. Show all posts
Showing posts with label alchemy. Show all posts

Saturday, August 26, 2023

Jabir ibn Hayyan

The previous post mentioned the man who discovered the combination of chemicals that dissolved gold. He could not have done that haphazardly; he had to have gained extensive knowledge of chemicals first. As it turns out, his works include the oldest known system for classifying chemicals.

His name was Abū Mūsā Jābir ibn Ḥayyān, and he lived in the 8th century...we think. To be fair, he does not get mentioned until the 10th century by a  Baghdad bibliographer who said Hayyan was a disciple of the Shi'ite Imam Ja'far al-Sādiq (who died in 765; Haiyan's writings refer to al-Sādiq as "my master"). That biographer assured his audience that Jabir existed, and made a list of his works, although many later Shi'ite biographers never mentioned Hayyan, and it is considered unlikely that he wrote the many hundreds of texts attributed to him.

Someone had to create the writings attributed to Hayyan, however, and perhaps the name was a pseudonym used to avoid the potential negative publicity because it looked like alchemy, which was rejected by many. Also, the works attributed to him are so many and varied that it is difficult to believe they were the work of one man. He may have inspired a "workshop" of students and followers who produced many of the works. Despite the confusion about his existence, a 271-page biography was written in the 20th century, and is readable at the Library of Congress website (if you can read Arabic, that is).

The body of work includes many techniques that are familiar to any high school student who has taken Chemistry: precipitation, crystallization, and distillation. It also teaches procedures for making apparatus (see the illustration) and equipment, for improving the quality of products such as steel, and how to reduce oxidation in metals. We learn from them how to dye and waterproof cotton and leather, the purification of gold, and how to treat cinnabar to extract pure mercury.

You may notice, in large sheets of glass used for, say, store fronts, that there is a greenish hue (most visible if you look at the edge of the glass sheet). Hayyan's writings explain how manganese oxide can be added to glass production to eliminate the greenish hue, resulting in a perfectly clear pane. These writings provide most of what is known about chemical analysis until the 16th century.

I want to go back to the question of Haiyan's identification. One of his writings implies an association with a certain family, the Barmakids. His 10th century biographer, Ibn al-Nadīm (c. 932–995), reports that Hayyan was devoted to Jaʿfar ibn Yaḥyā al-Barmakī, an Abbasid vizier. You may not recognize that name, but I promise you that you have heard of him. In fact, I promise 1001% that you have heard of him. With that teaser/clue, I'll see you tomorrow.

Friday, August 25, 2023

Magical Metal

Yesterday mentioned the gold and silver cramp rings used in the Middle Ages in England to avoid cramps and epilepsy. (The sample here—alas!—is a later iron version.) Gold and silver were precious not only for their rarity and beauty; it was the reason for their beauty that made them magical.

Gold and silver do not oxidize like iron and copper. This "metallic immortality" surely helped to enhance the idea that they were special in a magical way. In fact, gold was considered medicine by many early authorities.

An 11th century lecturer at Salerno, Constantinus Africanus, claimed:

Gold is more temperate than the other metals. It has the property of relieving a defective stomach and comforts the fearful and those who suffer from a heart complaint. Galen confirms that it is effective against melancholy and baldness.

 Obviously gold needed to be ingested for it to work. To do so required very small pieces, and the Arab physician Abulcasis explained the method for preparing gold for consumption:

Take a piece of good and pure gold; and have a plate with pure sweet water in front of you; and have a rough clean cloth of flax, one end of which you keep in your hand. The other end should stay soaking in water on the bottom of the plate. Then rub gold with the cloth, always moistening the cloth with water, and fine filings descend to the bottom of the container. Do so as long as much of that gold as you want to have been shaved. Then leave for an hour; and mix water speedily and wash three times and dry up and preserve it.

Gold-based preparations were called aurum potabile ("drinkable gold"), written about by Michael ScotRoger Bacon and others. Making it drinkable was no small trick, but it could be made into a liquid by combining hydrochloric acid and nitric acid. This mixture was one of the only ways to dissolve gold, and inspired alchemists to believe that an actual, pure aurum potabile was possible. Paracelsus (1493 - 1541), who was adamant that one could improve upon Nature, and his contemporary Johan Isaäc Hollandus were certain that pure liquid gold could be achieved and would have unbelievable curative properties.

The consumption of gold over time, however, far from enhancing health produced "auric fever": fever, profuse sweating, excess urination, gastrointestinal problems, and kidney damage. Evidence of death by gold has been found.

In 2013, The Geological Society published a collection of essays called A History of Geology and Medicine. One article, "Pharmaceutical use of gold from antiquity to the seventeenth century," points out that there is at least one modern medicine that includes gold: Myocrisin, an injectable used for rheumatoid arthritis.

Back to the subject of liquid gold: who figured out that hydrochloric and nitric could dissolve gold? That was a 9th century writer who produced the oldest known classification system of chemical substances. His name was Jabir ibn Hayyan, and you'll learn more about him next time.

Monday, February 21, 2022

Al-Kindi

Abu Yūsuf Yaʻqūb ibn ʼIsḥāq aṣ-Ṣabbāḥ al-Kindī (801-873CE) is called the Father of Arab philosophy. Born in Kufa and educated in Baghdad, he was instrumental in the translation of many Greek scholarly texts into Arabic. (Remember that a lot of classical scholarly knowledge came to Western Europe via Arabic translations.) He is also credited with introducing Indian numerals (what we mistakenly think of as Arabic numerals) into the Arab and western world.

He was a polymath who contributed to many fields, although he did not always find the scientific truth.

In astronomy he followed Ptolemy's geocentric theory of the solar system, and he was certain the planets followed circular orbits in obedience to God.

He was a chemist who debunked the idea of alchemy turning base metals into gold or silver. He was the first to distill pure ethanol, with which he created several perfumes. He also created cosmetics and pharmaceuticals, and wrote a book on the chemistry of perfume.

A recently discovered book of his in Istanbul, entitled (in English) A Manuscript on Deciphering Cryptographic Messages shows that he was a pioneer in cryptography with the first known explanation of how to decipher encrypted messages by analyzing the frequency of letters.

He wrote on pollution, environmentalism, and meteorology, and explained tides as a result of heating and cooling.

He published 15 treatise on music theory—five of which have survived—including the first known written use of the term "music" (musiqia); he urged the use of music in therapy.

In optics, he explained that both the eye and the object seen must be linked by a transparent medium (air) filled with light. He criticizes Anthemius of Trailes for reporting that sunlight could be focused in war to cause opposing warships to burst into flame. Anthemius did not witness it himself. Al-Kindi performed experiments to be certain this would actually work.

His theory that time, space, motion, and bodies were not absolutes but relative to other objects and the observer puts him closer to Einstein than to Galileo and Newton.

Although his belief that philosophy could support theology was contested by many Arabic scholars who followed him, his writings laid the groundwork much of Arabic philosophy to come.

He also applied mathematics to pharmacology, which I'll talk about tomorrow.

Friday, January 17, 2014

Scholar of the Supernatural

[I am on a brief vacation, so here is a post from the past. This post first appeared 23 August 2012.]

In Dante's Inferno, the eighth circle is reserved for sorcerers, astrologers, and false prophets. There the narrator sees Michael Scot. You might think, if someone were so well-known after his death, that we would know more about him. Well, we know a little, but we have some cool stories.

Michael Scot, depicted here tearing up the Scriptures.*
Michael Scot was no doubt born in Scotland, although other locations (like Salerno and Toldeo) have tried to claim him. Dates of 1175-c.1232 seem to work for what little we know of his life. We know that Pope Honorius wrote to Stephen Langton on 16 January 1223, urging him to grant Scot a religious position, and that Honorius himself nominated Scot for Archbishop of Cashel. If Scot was educated sufficiently to be offered these positions, he would not have lived until 1290, which is the date Sir Walter Scott offers for his death. (Scott was confusing Scot with a Sir Michael Scot who lived later.)

Scot turned down the position in Cashel; it looks like he did hold benefices in Italy, however, spending time in Bologna and Palermo before going to Toledo in Spain. It was probably in Spain that he learned Arabic, which helped get him invited to the court of Holy Roman Emperor Frederick II. Besides translating texts for Frederick, he was a court astrologer, saying of the work:
Every astrologer is worthy of praise and honor, since by such a doctrine as astrology he probably knows many secrets of God, and things which few know.
This was not likely to endear him to the Roman Catholic Church.

Although he was known in his lifetime as a brilliant Aristotelian scholar, and Fibonacci's Liber Abaci was dedicated to him, his books on alchemy and astrology and the occult sciences earned him a reputation for magic. A Bronze Age circle of stones in northwest England called "Long Meg and Her Daughters" was supposedly a coven of witches turned to stone by Scot. Other stories have him hosting feasts served by invisible spirits. Boccaccio refers to him in the Decameron as a magician. It is also told (long after the fact) that he predicted he would die from a small stone falling on his head from a great height. He always wore an iron cap to prevent it, but he removed the cap when entering a church one day (more not to stand out than for reverence of God, we are told), and a small stone of the size he predicted fell on his head. He picked up the stone, recognized that his prophecy was coming true, put his affairs in order, and died of the head wound shortly after! His reputation (helped by the dearth of facts) has made him a prime subject for fiction right up to the present day.

*From a fresco painted between 1366 and 1388 by Andrea Bonaiuti in the Cappellone degli Spagnoli of Santa Maria Novella in Florence. St. Dominic preaches to the crowd.

Friday, November 15, 2013

The Alchemist

Albertus Magnus and a hermaphrodite
from 
Symbola aureæ mensæ
We haven't talked about Albertus Magnus since his birthday last year. We really should address the subject for which he is usually known by people who don't know anything else about him: alchemy. Unfortunately, the evidence that he knew any alchemy comes from legends and documents that accrued to his reputation after his death. In fact, his own words are interpreted to deny the possibility of producing something by magic. He wrote ars non potest dare formam substantialem [Latin: "Art alone is not able to make a substantial form"]. Later generations, amazed by his vast knowledge, attributed many writings on alchemy to him. In the absence of any other authorial data, they are now attributed to "pseudo-Albertus Magnus."

There is, for instance, a legend that he managed to transform simple metal into gold, using the Philosopher's Stone. Supposedly, he gave the Stone to his pupil, Thomas Aquinas, prior to Magnus' death. The legend fails to take into account that Aquinas died six years before Magnus. The legend further states that Aquinas destroyed the Stone, fearing a connection with less-than-divine powers. This is recorded in a 1617 work on alchemy called Symbola aureæ mensæ [Latin: "Symbols of the golden table"], by Michael Maier. It is also said that he changed the weather of a winter day to a warm spring day with flowers blooming so that a party could be held outside.

He is also credited (supposedly according to eyewitnesses) with having created an automaton in his laboratory that could speak and perform menial tasks.

As for writings that we can firmly attribute to him, there is little there about alchemy. His De mineralibus [Latin: "Concerning minerals"] alludes to the occult power found in stones, but never explains what those powers might be. His chemical experiments seem to have led to the discovery of arsenic and silver nitrate.

His commentaries on Aristotle, and his ability to blend Aristotelian logic with Christianity, as well as his various (legitimate) experiments, gained him such a reputation for intelligence that it is not surprising that future authors would assume he achieved magical results.

Tuesday, December 18, 2012

Avicenna

In 1527, when the healer and alchemist Paracelsus wanted to display his contempt for tradition, he burned a book in the town square in Basle, where he had been appointed to the university by the town council. That book, allegedly, was The Canon of Medicine by Avicenna. Paracelsus had gone too far in rejecting what was still considered a fundamental work in western medicine. He was ejected from his post at the University, and from the town itself. Avicenna was too respected, even 500 years after he wrote his books.

Abū ʿAlī al-Ḥusayn ibn ʿAbd Allāh ibn Sīnā, called by the West Avicenna (c.980-1037), was mentioned here in the context of medicine. About 40 of the 240 surviving texts that he wrote (of a total of about 450!) deal with medicine. The encyclopedic Book of Healing and the Canon became standard textbooks for centuries.

The Canon assembled the best known medical knowledge to date, including Galen (129-c.200 CE) and Hippocrates (c.460-c.370 BCE) and adding a great deal of information that seems new to Avicenna. For instance:
The 'Qanun' is an immense encyclopedia of medicine. It contains some of the most illuminating thoughts pertaining to distinction of mediastinitis from pleurisy; contagious nature of phthisis*; distribution of diseases by water and soil; careful description of skin troubles; of sexual diseases and perversions; of nervous ailments. [George Sarton, Introduction to the History of Science]
Another reason why Paracelsus would want to burn Avicenna: Paracelsus was advertising his reputation as an alchemist, and believed that with salt, sulphur and mercury you should be able to produce anything. Avicenna, however, was completely opposed to the idea of alchemy, rejecting the notion that man could improve on Nature.

One could still work with Nature, however. Besides dealing with disease and injury (such as explaining how to judge how much healthy tissue could be removed during an amputation or the removal of cancerous tumors), Avicenna promoted restoring health, not just treating disease. He believed in the importance of physical exercise, of a good diet, and of a healthful environment.

Among other innovations, he lays the groundwork for modern ophthalmology, even suggesting that the optic nerves cross over each other. He laid out careful ground rules for the preparation, administration, and testing of drugs.

It has been called "one of the most significant intellectual phenomena of all times."** The Canon of Medicine is an essential part of any curriculum that studies the history of medicine.

*tuberculosis
**Swiss tuberculosis expert, Arnold Klebs

Thursday, November 15, 2012

Albertus Magnus & Astrology

Since the last two days have been about reconciling opposing views, and since today is the anniversary of the death of Albertus Magnus, it would probably be a good time to talk more about him.

Albertus Magnus (c.1200-1280) has only been mentioned so far in the context of rainbows, but he was involved in so much more than that. A German Dominican who became provincial of the order in 1254, he became so widely known for his learning that the term Magnus (The Great) was attached to his name in his lifetime by contemporaries such as Roger Bacon (also mentioned in the rainbow entries, as well as here). Although in the future the Dominicans would be nicknamed Domini canes (dogs of the Lord) and be put in charge of rooting out heresy, Albertus would actually spend part of his life writing to defend ideas that were considered heretical.

Most of the charges of heresy were coming from the University of Paris. The University issued a series of Condemnations between 1210 and 1277, condemning the teaching of ideas they considered heretical. Paris had no authority to universally condemn these teachings, however. In a twist that might seem very modern, this left other universities open to excellent marketing opportunities. The University of Toulouse invited students with "Those who wish to scrutinize the bosom of nature to the inmost can hear the books of Aristotle which were forbidden at Paris."

Attacking Aristotle was one way to raise the ire of Albertus. He had written commentaries on all available works of Aristotle, bringing that classical author more fully into the realm of accessible discussion. When Paris condemned the teaching of Aristotelian astrology as a threat to the notion of free will, Albertus had to get involved by writing the Speculum astronomiæ (Mirror on astronomy).* In this work, Albertus explains (using Aristotle's model of the heavens, of course), how the study of astrology and its predictive ability does not contravene God's Will or Free Will.

The order of the Heavenly Spheres
Between God's divine Will and human beings are the nine spheres of the heavens. As God's Will passes through each of the celestial and planetary spheres, it is tainted by exposure to those un-divine substances, just as water flowing down a stream can erode the banks and pick up silt. This has two results. One is that what we perceive in our study of astrology here from Earth is altered, meaning we are not looking directly at and anticipating God's intent for us. The other result is that, because the divine influence has been tainted or diluted by exposure to corporeal bodies, its influence is now corporeal; that is, it may affect our bodies, but not our souls. Astrological influence could make a man envious or prideful or lustful, and many people are content to just follow their impulses, but we have the ability to refuse to act on these impulses.

For Albertus, studying astrology helped to forewarn us about the influences that filtered down through the heavens, and gave us a chance to resist them. The Speculum became a central argument in favor of astrology for centuries, claiming that astrology helped us to understand and perfect our use of Free Will.

*There are numerous medieval works ascribed to Albertus Magnus with little proof, so modern scholars are cautious about claiming authorship; the Speculum has been disputed, but recent scholarship has found sufficient evidence to feel comfortable to claim it was by Albertus.